The theory of these curious phenomena is
very difficult to establish on account of the high temperatures which
are necessary for their manifestation, but it may be concluded, at
present, that nitrogen and probably oxygen also play some part in the
transportation of the silicon across the intervening space, and that the
carbosilicious compounds recently described by MM. Schuetzenberger and
Colson also take part in the phenomenon.--_Comptes Rendus_, xciv.,
1,710.--_Amer. Chem. Journal._
* * * * *
STANNOUS NITRATES.
At the Royal Powder Works at Spandau, Prussia, frequent ignition of the
powder at a certain stage of the process led to an examination of the
machinery, when it was found that where, at certain parts, bronze pieces
which were soldered were in constant contact with the moist powder, the
solder was much corroded and in part entirely destroyed, and that in the
joints had collected a substance which, on being scraped out with a
chisel, exploded with emission of sparks. It was suspected that the
formation of this explosive material was in some way connected with the
corrosion of the solder, and the subject was referred for investigation
to Rudolph Weber, of the School of Technology, at Berlin. The main
results of his investigation are here given.
The explosive properties of the substance indicated a probable
nitro-compound of one of the solder metals (tin and lead), and as the
lead salts are more stable and better understood than those of tin, it
was resolved to investigate the latter, in hope of obtaining a similar
explosive compound.
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